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Amide I Vibrational Dynamics of N -Methylacetamide in Polar Solvents: The Role of Electrostatic Interactions

✍ Scribed by DeCamp, M. F.; DeFlores, L.; McCracken, J. M.; Tokmakoff, A.; Kwac, K.; Cho, M.


Book ID
120539753
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
692 KB
Volume
109
Category
Article
ISSN
0022-3654

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Electrostatic origin of the cooperative
✍ Hajime Torii πŸ“‚ Article πŸ“… 2005 πŸ› Elsevier Science 🌐 English βš– 169 KB

The electric fields operating among the molecules in the oligomers of N-methylacetamide are analyzed to see the reasons for the cooperative effect on the CaO bond lengths and the diagonal force constants in the vibrational subspace of the amide I mode. It is suggested that the following three factor