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Amide Hydrolysis. Superimposed General Base Catalysis in the Cleavage of Anilides 1

โœ Scribed by Schowen, Richard L.; Zuorick, George W.

Book ID
121484082
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
339 KB
Volume
88
Category
Article
ISSN
0002-7863

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Superimposed general base catalysis in a
Superimposed general base catalysis in anilide hydrolysis
โœ Richard L. Schowen; George W. Zuorick ๐Ÿ“‚ Article ๐Ÿ“… 1965 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 106 KB

Biechler and Taft2 showed that 2,2,2-trifluoro-N-methylacetanilide (I) hydrolyzes at a rate given by eq. 1, and attributed the term second-order in hydroxide to the intermediacy of the dinegative ion II. -d[Il/dt = [II (k,[RO-I + kz[RO-12) (1) We have confirmed eq. 1 and have in addition shown by