Amide anion-initiated polymerization of methyl acrylate in aprotic solvents
β Scribed by Needles, Howard L. ;Johnson, Frederick A.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1968
- Tongue
- English
- Weight
- 268 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0449-2986
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## Abstract As the simplest model for the propagation centre in the anionic polymerization of methyl methacrylate, the solution of methyl 2βlithioisobutyrate (1) in tetrahydrofuran was studied by means of ^1^H, ^6^Li, ^7^Li and ^13^C nuclear magnetic resonance (NMR), and Raman spectroscopy at vario
The kinetics of methyl acrylate (MA) polymerization initiated by a V(V)-Cyclohexanone redox system, in the presence of surfactant, over a temperature range of 30-50ΠC in acidic medium are analyzed. The anionic surfactant (SDS) enhances the rate of polymerization ( R p ) as well as the rate of V(V) c