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Ambiguity of spectroscopic parameters in the case of accidental vibration—rotation resonances in tetrahedral molecules. r2J and r2J2 terms for E-F2 interacting states

✍ Scribed by V.I. Perevalov; Vl.G. Tyuterev; B.I. Zhilinskii

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
479 KB
Volume
104
Category
Article
ISSN
0009-2614

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✦ Synopsis

The ambiguity of spectroscopic parameters in the case of accidental vibration-rotation resonances in tetrahedral molecules is discussed_ Equations are derived which relate different possible sets of r2rqJ and &* and rzJ* parameters obtained by fitting to experimental data. Perturbation calculations are generallzed to give formulae consistent with various sets of fitted parameters for interacting v2 and ~4 band of **CH4.

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✍ Perdue, Adoline S. ;Bell, Frances ;Starnes, W.R. ;Hitchcock, Philip ;Teague, R.S 📂 Article 📅 1950 🏛 Elsevier ⚖ 346 KB 👁 1 views