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Ambident electrophilicity of O,O-diethyl-S-phenyl phosphorothiolate

โœ Scribed by Hendrik V. Garbers; Tomasz A. Modro


Book ID
102234624
Publisher
John Wiley and Sons
Year
1990
Tongue
English
Weight
285 KB
Volume
1
Category
Article
ISSN
1042-7163

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โœฆ Synopsis


Reaction between 0,O-diethyl-S-phenyl phosphorothiolate and lithium dialkylamides results in the displacement of the PhS substituent by the R2N group. With Grignard reagents, the same substrate

gives products of the nucleophilic substitution at both the phosphorus and the sulfur atom.


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