Aluminumdodecatungstophosphate (AlPW12O40) as a reusable Lewis acid catalyst: Facile regioselective ring opening of epoxides with alcohols, acetic acid and thiols
โ Scribed by Habib Firouzabadi; Nasser Iranpoor; Abbas Ali Jafari; Somayeh Makarem
- Book ID
- 104056992
- Publisher
- Elsevier Science
- Year
- 2006
- Tongue
- English
- Weight
- 141 KB
- Volume
- 250
- Category
- Article
- ISSN
- 1381-1169
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โฆ Synopsis
AlPW 12 O 40 as a recyclable Lewis acid and stable solid compound was introduced for efficient ring opening of different epoxides with thiols, acetic acid, and primary, secondary, and tertiary alcohols. These processes were carried out at room temperature with high regio-and stereoselectivity.
๐ SIMILAR VOLUMES
AlPW 12 O 40 as a highly water tolerant Lewis acid is a suitable catalyst for the condensations in which water molecules generated in the process of the reaction. Therefore, efficient etherification of different classes of alcohols was performed using catalytic amounts of AlPW 12 O 40 . Preparation