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Aluminumdodecatungstophosphate (AlPW12O40) as a reusable Lewis acid catalyst: Facile regioselective ring opening of epoxides with alcohols, acetic acid and thiols

โœ Scribed by Habib Firouzabadi; Nasser Iranpoor; Abbas Ali Jafari; Somayeh Makarem


Book ID
104056992
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
141 KB
Volume
250
Category
Article
ISSN
1381-1169

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โœฆ Synopsis


AlPW 12 O 40 as a recyclable Lewis acid and stable solid compound was introduced for efficient ring opening of different epoxides with thiols, acetic acid, and primary, secondary, and tertiary alcohols. These processes were carried out at room temperature with high regio-and stereoselectivity.


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โœ Habib Firouzabadi; Nasser Iranpoor; Abbas Ali Jafari ๐Ÿ“‚ Article ๐Ÿ“… 2005 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 85 KB

AlPW 12 O 40 as a highly water tolerant Lewis acid is a suitable catalyst for the condensations in which water molecules generated in the process of the reaction. Therefore, efficient etherification of different classes of alcohols was performed using catalytic amounts of AlPW 12 O 40 . Preparation