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Aluminum Alkyl Complexes Containing Guanidinate Ligands

✍ Scribed by Aeilts, Sarah L.; Coles, Martyn P.; Swenson, Dale C.; Jordan, Richard F.; Young, Victor G.

Book ID
127292595
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
175 KB
Volume
17
Category
Article
ISSN
0276-7333

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Chloro, Alkyl and Aryl Complexes of Rare
Chloro, Alkyl and Aryl Complexes of Rare Earth Metals Supported by Bulky Tetrasubstituted Guanidinate Ligands
✍ Alexander A. Trifonov; Dmitrii M. Lyubov; Elena A. Fedorova; Georgy K. Fukin; He 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 221 KB

## Abstract The reactions of anhydrous LnCl~3~ (Ln = Y, Nd, Sm, Lu) with two equiv. of sodium __N__,__N′__‐dicyclohexyl‐__N′′__‐bis(trimethylsilyl)guanidinate Na[(Me~3~Si)~2~NC(NCy)~2~], obtained from Na[N(SiMe~3~)~2~] and the 1,3‐dicyclohexyl‐substituted carbodiimide CyN=C=NCy in THF, yield the mo