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Aluminium substitution in iron(II–III)-layered double hydroxides: Formation and cationic order

✍ Scribed by Christian Ruby; Mustapha Abdelmoula; Rabha Aissa; Ghouti Medjahdi; Michela Brunelli; Michel François

Book ID
104030174
Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
870 KB
Volume
181
Category
Article
ISSN
0022-4596

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A pure pyroaurite-type compound (PTC) with the composition \(\left.\left[\mathrm{Co}_{5.42}^{\mathrm{II}} \mathrm{Fe}_{2.47}^{\text {III }}(\mathrm{OH})_{16}\right]\left(\mathrm{CO}_{3}\right)_{1.12} x \mathrm{H}_{2} \mathrm{O}\right](x=5-6)\) has been synthesized by air oxidation of \(\mathrm{Fe}(\