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Aluminium Nitrate Nonahydrate (Al(NO3)3⋅9 H2O): An Efficient Oxidant Catalyst for the One-Pot Synthesis of Biginelli Compounds from Benzyl Alcohols

✍ Scribed by Eskandar Kolvari; Mohammad Ali Zolfigol; Maryam Mirzaeean


Publisher
John Wiley and Sons
Year
2012
Tongue
German
Weight
138 KB
Volume
95
Category
Article
ISSN
0018-019X

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✦ Synopsis


Abstract

A clean and efficient tandem oxidative cyclocondensation process is reported for the synthesis of 3,4‐dihydropyrimidin‐2(1__H__)‐one or ‐thione derivatives from primary aryl alcohols, β‐keto esters, and urea or thiourea in the presence of Al(NO~3~)~3~⋅9 H~2~O as oxidant catalyst (Scheme, Table 5).