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Alternative molecularly imprinted polymeric membranes from a tetrapeptide residue consisting of D- or L-amino acids

✍ Scribed by Masakazu Yoshikawa; Jun-ichiro Izumi; Toshio Kitao; Shunji Sakamoto


Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
326 KB
Volume
18
Category
Article
ISSN
1022-1336

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✦ Synopsis


Abstract

Alternative molecularly imprinted polymeric membranes were prepared from a polystyrene resin bearing tetrapeptides consisting of D‐amino acids or L‐amino acids. The membrane prepared from a DLDE derivative (H‐Asp(OcHex)‐Leu‐Asp(OcHex)‐Glu(OBzl)CH~2~) consisting of D‐amino acids and imprinted by Boc‐D‐Trp recognizes the D‐isomer in preference to the corresponding L‐isomer and vice versa. The amino acid preferentially adsorbed by the membrane was selectively permeated by applying electrodialysis.