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Alternative Mechanisms of the Alkyne to Vinylidene Isomerization Promoted by Half-Sandwich Ruthenium Complexes. X-ray Crystal Structures of [CpRuCCHCOOMe(dippe)][BPh 4 ] and [CpRuH(C⋮CCOOMe)(dippe)][BPh 4 ] (dippe = 1,2-bis(diisopropylphosphino)ethane; Cp* = C 5 Me 5 )

✍ Scribed by de los Ríos, Isaac; Tenorio, Manuel Jiménez; Puerta, M. Carmen; Valerga, Pedro

No coin nor oath required. For personal study only.

Alternative Mechanisms of the Alkyne to Vinylidene Isomerization Promoted by Half-Sandwich Ruthenium Complexes. X-ray Crystal Structures of [Cp*RuCCHCOOMe(dippe)][BPh 4 ] and [Cp*RuH(C⋮CCOOMe)(dippe)][BPh 4 ] (dippe = 1,2-bis(diisopropylphosphino)ethane; Cp* = C 5 Me 5 )