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Alternative Low-Energy Mechanisms for Isotopic Exchange in Gas-Phase D2O–H+(H2O)n Reactions

✍ Scribed by Massimo Mella; Alessandro Ponti


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
247 KB
Volume
7
Category
Article
ISSN
1439-4235

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Kinetic study of the isotope exchange re
✍ M.-C. Hsu; J.-J. Jwo 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 144 KB 👁 2 views

The kinetics of the isotope exchange reactions of RCH(COOH) 2 (R"H, D, Me, Et, Bu, and Ph) in D 2 O solution were studied by using 1 H NMR spectroscopy. It was observed that the rate of isotope exchange reaction was inhibited by the presence of 1 M of DNO 3 , DCl, DBr or D 2 SO 4 and catalyzed by th