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Alternating terpolymerization of three non-homopolymerizable monomers

✍ Scribed by Dietrich Braun; Matthias Schacht; Hartmut Elsässer; Ferenc Tüdős

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
362 KB
Volume
18
Category
Article
ISSN
1022-1336

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✦ Synopsis

Abstract

The free‐radical terpolymerization of maleic anhydride (MSA), isobutyl vinyl ether (VIBE) and anethol (ANE) at 60°C is described. These three monomers do not homopolymerize under the conditions used. Binary copolymers are only obtained from MSA and one of the two investigated donor monomers, whereas the binary copolymerization of VIBE with ANE is not possible. In all terpolymers from these three non‐homopolymerizable monomers the MSA content amounts to about 50 mol‐%; VIBE is about twice as reactive as ANE. The terpolymerization can formally also be described under the assumption that two binary complexes (MSA/ANE (I) and MSA/VIBE (II)) are copolymerized. For this case the reactivity ratios r~I~ = 0,9 and r~II~ = 1,7 are obtained.

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