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Alternating Ethylene−Styrene Copolymerization with a Methylaluminoxane-Free Half-Titanocene Catalyst

✍ Scribed by Pellecchia, Claudio; Pappalardo, Daniela; D'Arc, Michelina; Zambelli, Adolfo

Book ID
126153820
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
590 KB
Volume
29
Category
Article
ISSN
0024-9297

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The copolymerization of styrene and ethylene was attempted in the presence of the catalytic system CpTiCl,methylaluminoxane. Polymerizations were carried out at different polymerization temperatures and Al/Ti mole ratios. The structure of the polymer was investigated with FTIR, DSC, GPC, and "C-NMR