Alternating copolymerization of ethylene with carbon monoxide on a supported palladium catalyst
✍ Scribed by O. M. Chukanova; Yu. M. Shul’ga; G. P. Belov
- Book ID
- 111469204
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2009
- Tongue
- English
- Weight
- 222 KB
- Volume
- 51
- Category
- Article
- ISSN
- 1560-0904
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Carbon monoxide (CO) and norbornadiene (NBD) with Pd(CH 3 CN) 4 (BF 4 ) 2 were copolymerized under various conditions at 50ЊC. Elemental analysis, infrared spectra, UV, Raman, and NMR spectra showed that the copolymers contained both ketone and unsaturated ring structures. Bidentate nitrogen ligands
In this work, carbon monoxide (CO) and 4-vinylcyclohexene (VCH) with [Pd(CH 3 CN) 4 ](BF 4 ) 2 were copolymerized under various conditions at 60ЊC. Elemental analysis and infrared, UV, and NMR spectra indicated that copolymers containing a ketone and a cyclic structure of cyclohexyl and norbornane g