Alternant molecular orbital treatment of the allyl cation, radical and anion
โ Scribed by Chong, D.P.; Linnett, J.W.
- Book ID
- 126616232
- Publisher
- Taylor and Francis Group
- Year
- 1964
- Tongue
- English
- Weight
- 274 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0026-8976
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๐ SIMILAR VOLUMES
An adequate description of the electronic structure of anions poses an important challenge for the computational chemist.' The purpose of the present work is to explain how substituted vinyl anions (l,X=OR) can be stabilized relative to the isoelectronic substituted ally1 anions @,X=OR). Recent expe
The orbital energy second derivatives with respect to the CC asymmetric stretching mode of benzene, allyl cation and allyl anion show unambigiously that the ~r orbitals are unstable with respect to a distorted geometry with alternating CC bonds. It is the cr frame which enforces the D6h form of benz