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Alteration of the Reactivity of a Tellurophene Within a Core-Modified Porphyrin Environment: Synthesis and Oxidation of 21-Telluraporphyrin

✍ Scribed by Prof. Dr. Lechoslaw Latos-Grażyński; Ewa Pacholska; Dr. Piotr J. Chmielewski; Dr. Marilyn M. Olmstead; Prof. Dr. Alan L. Balch


Book ID
101557146
Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
367 KB
Volume
34
Category
Article
ISSN
0044-8249

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Oxidation of olefins by palladium(II). P
✍ John W. Francis; Patrick M. Henry 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 899 KB

In the absence of CuC12, ethene was oxidized to ethanal by PdCl,(pyridine) -in aqueous solution by the rate expression: \* where K' is the equilibrium constant for n-complex formation between ethene and PdCl,(Py) -(Py =pyridine). This rate expression is of the same form as that previously found for