.alpha.-Deuterium isotope effects on the solvolyses of norbornyl brosylates and synthesis of labeled norbornyl derivatives
โ Scribed by Murr, Brown L.; Conkling, J. A.
- Book ID
- 127229670
- Publisher
- American Chemical Society
- Year
- 1970
- Tongue
- English
- Weight
- 376 KB
- Volume
- 92
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The synthesis .from l4CC0, of various endo-and exo-3-I4Cdehydro-2-norbornyl and 2-norbornyl derivatives, suitable for use in isotopic scrambling studies, is described. ## INTRODUCTION. In the original work of Roberts and coworkers ( l , 2, on the solvolyses of exo-and end0-2,3-~~C,-2-norbornyl br
## The r e c e n t l y r e p o r t e d s y n t h e a i s o f C-3 l a b e l e d dehydro-2-norbornyt and 2-norbornyt d e r i v a t i v e s ( 1 ) was found t o be i n e r r o r . Only about 7 0 % o f t h e " C -l a b e l was l o c a t e d a t C-3, t h e o t h e r 30% b e i n g found a t C-2. One o f t