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.alpha.-Deuterium isotope effect for displacement of the nitrate group

โœ Scribed by Koshy, K. M.; Robertson, R. E.

Book ID
127129285
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
380 KB
Volume
96
Category
Article
ISSN
0002-7863

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Stereochemical requirements for the beta-deuterium isotope effect in the SN1 displacement of vinyl esters
โœ D.D. Maness; L.D. Turrentine ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 157 KB

Available evidence(l) indicates that under normal SN~ solvolytlc condltlons a vinyl cation of linear configuration 1s the thermodynamically favored intermediate. The stereochemical course of the reaction path from product-forming intermediate to product is thus described At this time no lnformatlon