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Alpha carbocation stabilization by silicon, germanium and tin

✍ Scribed by John A. Soderquist; Alfred Hassner

Book ID: 104217515
Publisher: Elsevier Science
Year: 1988
Tongue: French
Weight: 372 KB
Volume: 29
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)82072-9

No coin nor oath required. For personal study only.

✦ Synopsis

The hydrolyses of a number of a-metalloidal vinyl ethers were found to undeqo a mtelfmittng protonatfon to produce a-siZyL gennyl or stannyl carboc&ns.

Compamtiw rate data &ads to the ordering: c>Sn>GeMbH, jbr the stabflizatIon of such intemwd@s.

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