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Aloperine: Stereocontrolled Synthesis of Two Stereoisomers and Determination of Absolute Configuration

✍ Scribed by Brosius, Arthur D.; Overman, Larry E.

Book ID
120499130
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
190 KB
Volume
62
Category
Article
ISSN
0022-3263

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## Abstract The synthesis of 3,4‐didehydroionone isomers **4**, (+)‐**6**, and (βˆ’)‐**6** and of 3,4‐didehydro‐7,8‐dihydroionone isomers **5**, (+)‐**7**, and (βˆ’)‐**7** was accomplished starting from commercially available racemic __Ξ±__‐ionone (**1**). Their preparation of the racemic forms **4**–**