✦ LIBER ✦

Allylstannation: IX. The preparation of 4-chloro-2,6-dialkyl-, 4-bromo-2,6-dialkyl-, (E/Z)-4-chloro-2,6-dialkyl-3-methyl-and (E/Z)-4-bromo-2,6-dialkyl-3-methyl-tetrahydropyrans by condensation of aldehydes with di- and tri-halides of allyltin

✍ Scribed by Andrea Boaretto; Donatella Furlani; Daniele Marton; Giuseppe Tagliavini; Alessandro Gambaro

Publisher: Elsevier Science
Year: 1986
Tongue: English
Weight: 620 KB
Volume: 299
Category: Article
ISSN: 0022-328X
DOI: 10.1016/0022-328x(86)82011-3

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Allylstannation III. Synthesis of homoal

Allylstannation III. Synthesis of homoallylic alcohols and 4-chloro-2,6-dialkyl-3-methyltetrahydropyrans by reactions between (E/Z)-2-butenyldichloro-n-butyltin and aldehydes

✍ Alessandro Gambaro; Andrea Boaretto; Daniele Marton; Giuseppe Tagliavini 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 667 KB

ChemInform Abstract: Reactions of Dialky

ChemInform Abstract: Reactions of Dialkyl 4-Bromo-2,2-dimethyl-3-oxohexane-1,6-dioates, -heptane-1,7-dioates with Zinc and Aromatic Aldehydes.

✍ V. V. Shchepin; S. V. Nikitin; S. A. Filimonov; N. Yu. Russkikh; P. S. Silaichev 📂 Article 📅 2008 🏛 John Wiley and Sons ⚖ 37 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

Synthesis of 4, 6-dialkyl-1,3-dioxins. V

Synthesis of 4, 6-dialkyl-1,3-dioxins. Versatile intermidiates for the preparation of (E)-alkenones, anti,anti-1, 2, 3-triols and syn-1, 3-diols

✍ Raymond L Funk; Gary L Bolton 📂 Article 📅 1988 🏛 Elsevier Science 🌐 French ⚖ 271 KB

The title compounds 4 are prepared from 4-alkyldioxins 2 via a metalation, alkylation sequence. The dialkyl dioxins 4 are thermally labile (providing enones) and undergo highly stereoselective hydroboration or hydrogenation reactions to provide enti,anti-1,2,3-triols and syn-1,3-diols, respectively.

Preparation of methyl 4,6-O-benzylidene-

Preparation of methyl 4,6-O-benzylidene-2-chloro- and -2-bromo-α- and β-d-xylo-hexopyranosid-3-uloses and their α-d-ribo isomers, and formation of glycosid-3-ulose hydrates for the β-d-xylo isomers

✍ Tohru Sakakibara; Toshio Nakagawa 📂 Article 📅 1989 🏛 Elsevier Science 🌐 English ⚖ 772 KB

The title glycosid-Iuloses were prepared from 3-nitro-@-D-three-hex-2-enopyranoside derivatives. 'H-N.m.r. spectral studies revealed that the 2-bromo-and 2-chloro-P-D-xylo-hexopyranosid-3-uloses readily equilibrated with their hydrates, but the remaining glycosid-3-uloses, including the cy-D-xylo an

ChemInform Abstract: Easy Access to (E,Z

ChemInform Abstract: Easy Access to (E,Z)-β-Nitro-α,β-olefinated Hydrazones, 6-Oxo-1,6-dihydropyridazines, and 4-Chloro-1-aminopyrroles by Domino Reactions of 1,2-Diaza-1,3-butadienes with Halogen-Coactivated Methylene or Methine Compounds.

✍ Orazio A. Attanasi; Roberto Ballini; Lucia De Crescentini; Paolino Filippone; Fa 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 35 KB 👁 1 views

Structural Characterization and Intramol

Structural Characterization and Intramolecular Aliphatic C−H Oxidation Ability of MIII(μ-O)2MIII Complexes of Ni and Co with the Hydrotris(3,5-dialkyl-4-X-pyrazolyl)borate Ligands Tp3.0.CO;2-C/asset/equation/tex2gif-sup-3.gif?v=1&t=h5lp536o&s=a03c9eb1fe277a993afb16d61a4b5e5e1fd6ae14" class="inlineGraphic"> (X=Me, H, Br) and Tp3.0.CO;2-C/asset/equation/tex2gif-sup-4.gif?v=1&t=h5lp536o&s=f62756419e66415fd41eb92c51dc480468265b22" class="inlineGraphic">

✍ Shiro Hikichi; Michito Yoshizawa; Yasuyuki Sasakura; Hidehito Komatsuzaki; Yoshi 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 531 KB

The nickel complex 2 Ni shows reactivity about 10 3 times greater than that of the cobalt analogue 2 Co . The oxidation ability of the M III (m-O) 2 M III core should be affected by the hindered Tp R ligand system, which can stabilize the 2 oxidation state of the metal centers.