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Allylstannane Allylation of Aldimines Activated by Chlorotrimethylsilane

โœ Scribed by De-Kun Wang; Li-Xin Dai; Xue-Long Hou


Book ID
103409980
Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
200 KB
Volume
36
Category
Article
ISSN
0040-4039

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Allylation of aldimines promoted by NbCl
โœ Carlos Kleber Z Andrade; Guilherme R Oliveira ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 142 KB

Niobium chloride promoted the addition of allylstannanes to aromatic aldimines. Excellent syn diastereoselectivity was obtained in the addition of crotylstannane to N-benzylideneaniline (46:1).