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Allylsilylation of Carbon−Carbon and Carbon−Oxygen Unsaturated Bonds via a Radical Process 1

✍ Scribed by Miura, Katsukiyo; Saito, Hiroshi; Nakagawa, Takahiro; Hondo, Takeshi; Tateiwa, Jun-ichi; Sonoda, Motohiro; Hosomi, Akira

Book ID: 126917535
Publisher: American Chemical Society
Year: 1998
Tongue: English
Weight: 46 KB
Volume: 63
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo981027s

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## Abstract The reactions of an isolable dialkylsilylene, 2,2,5,5‐tetrakis(trimethylsilyl)silacyclopentan‐1,1‐diyl (**1**) with ethylene, (Z)‐2‐butene, acetylene, bis(trimethylsilyl)acetylene, and 2,3‐dimethylbutadiene at room temperature gave the corresponding silacycles as isolable compounds. Bec