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Allyloxycarbanions, cyclizations to vinyl oxetanes.

โœ Scribed by W.Clark Still

Book ID
104225758
Publisher
Elsevier Science
Year
1976
Tongue
French
Weight
237 KB
Volume
17
Category
Article
ISSN
0040-4039

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โœ Ilhyong Ryu; Shin-ichi Ogura; Satoshi Minakata; Mitsuo Komatsu ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 216 KB

When 5-exo/6-endo type of vinyl radical cyclization onto aldimine N=C bond was examined using tin hydride mediated radical reaction conditions, selective 6-endo cyclization took place to lead to 3-methylenepiperidines. On the other hand, vinyl radical cyclization onto ketimine N=C bond did not take