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Allylic rearrangements during nucleophilic substitution reactions in 1-hydroxy-1-phenyl-2-propen-1-ylcyclopentadienylmanganese tricarbonyl

✍ Scribed by K. N. Anisimov; N. E. Kolobova; I. B. Zlotina; G. G. Dvoryantseva


Book ID
112419923
Publisher
Springer
Year
1966
Tongue
English
Weight
262 KB
Volume
15
Category
Article
ISSN
1573-9171

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Substituted pyridopyrimidinones. Part 5.
✍ Mohamed Abass; Mostafa M. Ismail; Wafaa R. Abdel-Monem; Aisha S. Mayas πŸ“‚ Article πŸ“… 2010 πŸ› Versita 🌐 English βš– 491 KB

## Abstract Reactivity of 2-hydroxy-4-oxo-4H-pyrido[1,2-a]pyrimidine-3-carbaldehyde (I) towards N- and C-nucleophiles was described. A series of new enaminones II–III, Schiff’s base IV, and hydrazinomethylenediketones V–VIII and X were prepared in good yields. Cyclization of compounds X was achieve