Allylic radicals with captodative substitution : Easy homolysis of 1,5-hexadienes.
✍ Scribed by M. Van Hoecke; A. Borghese; J. Penelle; R. Merényi; H.G. Viehe
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- French
- Weight
- 228 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0040-4039
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pToluenethiol/oxygen co-oxidation of 5-methylhepta-1,3,6-triene (2) gives inter alia only one (@) of four possible diastereoisomeric dioxolanes, and the threo-and erythro-isomers of the 1,4-addition product (l,O, 1,). The variation in relative yield= thiol concentration indicates that coupling of th
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