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Allylic oxidation with 3,5-dimethylpyrazole. Chromium trioxide complex steroidal .DELTA.5-7-ketones

โœ Scribed by Salmond, William G.; Barta, Mary A.; Havens, Jeffrey L.


Book ID
118207575
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
437 KB
Volume
43
Category
Article
ISSN
0022-3263

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Chromium trioxide-3, 5-dimethylpyrazole
โœ E.J. Corey; G.W.J. Fleet ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 162 KB

A wide range of alcohols can be oxidized efficiently and conveniently by a complex of chromium trioxide and 3,5\_dimethylpyrazole. Addition of one equivalent of 3,5\_dimethylpyrazole to a suspension o chromium trioxide in methylene chloride at room temperature forms a dark red solution; almost all