Allylic oxidation of olefins to the corresponding α,β-unsaturated ketones catalyzed by chromium aluminophosphate-5
✍ Scribed by H.E.B. Lempers; R.A. Sheldon
- Book ID
- 103964473
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 325 KB
- Volume
- 143
- Category
- Article
- ISSN
- 0926-860X
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📜 SIMILAR VOLUMES
Allylic alcohols are obtained with an unprecedented simple method by chemosebctive hydrogen transfer reduction of a,$ unsaturated ketones catalyzed by MgC.
IN a previous communication' we reported the conversion of steroidal 4-enand 4,6-dien-J-ones into the corresponding 1,4-dien and 1,4,6-trien-j-ones
Enol acetates derived from saturated ketones are converted to a,&unsaturated ketones by heating with ally1 methyl carbonate in MeCN by bimetallic catalysis of palladiumphosphine complex and tin methoxide. Conversion of saturated ketones to corresponding a,&unsaturated ketones is an important synthet