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Allylic oxidation of olefins to the corresponding α,β-unsaturated ketones catalyzed by chromium aluminophosphate-5

✍ Scribed by H.E.B. Lempers; R.A. Sheldon


Book ID
103964473
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
325 KB
Volume
143
Category
Article
ISSN
0926-860X

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One-step synthesis of α,β-unsaturated ke
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Enol acetates derived from saturated ketones are converted to a,&unsaturated ketones by heating with ally1 methyl carbonate in MeCN by bimetallic catalysis of palladiumphosphine complex and tin methoxide. Conversion of saturated ketones to corresponding a,&unsaturated ketones is an important synthet