Secondary allylic acetates are the almost exclusive kinetically-controlled products formed in the oxidation of both l-and 2-olefins by Hg(OAcj2 in AcOH.~ Ape& of equilibrating primary and secondary allylic mercuric acetates, with the equilibrium being overwhelmingly on the side of the former were su
โฆ LIBER โฆ
Allylic oxidation of olefins by mercuric acetate
โ Scribed by Zvi Rappoport; Paul D. Sleezer; S. Winstein; W.G. Young
- Book ID
- 104250032
- Publisher
- Elsevier Science
- Year
- 1965
- Tongue
- French
- Weight
- 477 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0040-4039
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## Abstract For Abstract see ChemInform Abstract in Full Text.
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Oxymercuration is a well known and well understood reaction of mercuric salts with olefins which involves addition to the double bond via a cyclic mercurinium ion (1). A variant