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Allylic oxidation of olefins by mercuric acetate

โœ Scribed by Zvi Rappoport; Paul D. Sleezer; S. Winstein; W.G. Young


Book ID
104250032
Publisher
Elsevier Science
Year
1965
Tongue
French
Weight
477 KB
Volume
6
Category
Article
ISSN
0040-4039

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Allylic oxidation of allylbenzene by mer
โœ Zvi Rappoport; L.K. Dyall; S. Winstein; W.G. Young ๐Ÿ“‚ Article ๐Ÿ“… 1970 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 308 KB

Secondary allylic acetates are the almost exclusive kinetically-controlled products formed in the oxidation of both l-and 2-olefins by Hg(OAcj2 in AcOH.~ Ape& of equilibrating primary and secondary allylic mercuric acetates, with the equilibrium being overwhelmingly on the side of the former were su