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Allylic organometallic way to control acyclic stereochemistry and its application to the synthesis of carbohydrates

โœ Scribed by Yoshinori Yamamoto; Toshiaki Komatsu; Kazuhiro Maruyama


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
742 KB
Volume
285
Category
Article
ISSN
0022-328X

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## Introduction of the a-fluorophosphonomethyl ether functionality has been achieved by electro~hilic fluorination of the corresponding phosphonomethyl ether carbanion. Coupling of the synthesized 2-[(diethoxyphosphono)fluoromethoxy]ethanol ( 9 ) with adenine and 6-chloropurine under Mitsunobu