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Allylic Amination and Aziridination of Olefins by Aryl Azides Catalyzed by CoII(tpp): A Synthetic and Mechanistic Study

✍ Scribed by Alessandro Caselli; Emma Gallo; Simone Fantauzzi; Simona Morlacchi; Fabio Ragaini; Sergio Cenini


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
344 KB
Volume
2008
Category
Article
ISSN
1434-1948

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The kinetics of oxidation of the aliphatic primary amines, n-propylamine, n-butylamine, and isoamylamine, by N-sodio-N-bromobenznesulfonamide or bromamine-B (BAB), in the presence of osmium(VIII), has been studied in alkaline medium at 35ЊC. In the presence of the catalyst, the experimental rate law