Allylboration polymerization. 1. Synthesis of boron-containing polymers by the reaction between triallylborane and dicyano compounds
โ Scribed by Chujo, Yoshiki; Tomita, Ikuyoshi; Saegusa, Takeo
- Book ID
- 126231258
- Publisher
- American Chemical Society
- Year
- 1992
- Tongue
- English
- Weight
- 236 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0024-9297
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The polymerization of 2-methylpropene (MP) initiated by the system di(l-azido-l-methylethyl)-1,4-benzene (DAMEB)/boron trichloride in CH,CI, solution was carried out at different temperatures and with different ratios R = [BCl,]/[DAMEB]. At low temperature and for R higher than 2, the functionalitie
## Abstract Polymerizations of 2โmethylpropene (MP) initiated by the system 1,4โbis(1โazidoโ1โmethylethyl)benzene (DAMEB)/BCl~3~ in the presence of DMSO were carried out by โall monomer inโ (AMI) technique at โ70ยฐC in CH~2~Cl~2~ solution. FTโIR, ^1^H NMR and SEC analyses of polymers (PMP) showed th