𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Allylborane and its isomers. An ab initio study of the C3BH7 potential energy surface, the barrier to 1,3-shifts in allylboranes, and nonclassical boracyclobutane, cyclopropylborane, and vinylborane structures

✍ Scribed by Buehl, Michael; Schleyer, Paul von R.; Ibrahim, Mustafa A.; Clark, Timothy


Book ID
127322315
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
757 KB
Volume
113
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Vinyloxyborane and its isomers. An ab in
✍ Mustafa R. Ibrahim; Michael BΓΌhl; Reinhard Knab; Paul Von Rague Schleyer πŸ“‚ Article πŸ“… 1992 πŸ› John Wiley and Sons 🌐 English βš– 433 KB

Vinyloxyboranes, CH2=CH-O-BR2, are shown by ab initio molecular orbital theory to be more stable than the isomeric p-aldoboranes, R2B-CH2-CH=O, by ca. 19 kcal/mol. The MP2/6-31G\*/6-31G\* + ZPE barrier for the [1,3] boron shift is only 10.9 kcal/mol (R = Me) relative to the aldoborane. Other C,H,BO