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Allyl rearrangement in some substituted polyhaloallyl alcohols

✍ Scribed by L. I. Zakharkin

Book ID
112491562
Publisher
Springer
Year
1956
Tongue
English
Weight
977 KB
Volume
5
Category
Article
ISSN
1573-9171

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πŸ“œ SIMILAR VOLUMES

New 1,3-Disubstituted Enantiomerically P
New 1,3-Disubstituted Enantiomerically Pure Allylboronic Esters by Johnson Rearrangement of Boron-Substituted Allyl Alcohols
✍ JΓΆrg Pietruszka; Niklas SchΓΆne πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 209 KB

## Abstract Starting from commercially available 1‐substituted propargylic alcohols **6**, **18** and __ent__**‐18**, stable enantio‐ and diastereomerically pure 1,3‐disubstituted allylboronic esters **10**, **19** and **20** were synthesized. The key step βˆ’ a Johnson rearrangement βˆ’ was highly dia