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Allyl Ethers of Carbohydrates. I. Preparation and Polymerization of Tetra-allyl α-Methyl Glucoside

✍ Scribed by Nichols, P. L.; Yanovsky, E.

Book ID
121462345
Publisher
American Chemical Society
Year
1944
Tongue
English
Weight
373 KB
Volume
66
Category
Article
ISSN
0002-7863

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Transition metal-catalyzed tandem isomer
Transition metal-catalyzed tandem isomerization and cationic polymerization of allyl ethers. I. Discovery and scope
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Allyl ethers are readily polymerized using a new polymerization reaction termed: transition metal-catalyzed tandem isomerization and cationic polymerization. Employing dicobalt octacarbonyl in combination with organosilanes, polymerization takes place rapidly and exothermically to give high molecula