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Allowed transitions and the dipole moment of HD+

✍ Scribed by P.R. Bunker

Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
273 KB
Volume
27
Category
Article
ISSN
0009-2614

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✦ Synopsis

Within the Born-Oppenhcrmer approximation homopolar isotopically unsymmetric diatomic ions (ND', 14N1'N+, 35C137C1+, etc.) have D _h symmetry and a non-vanishing dipole moment. This apparent paradox is reconciled here by treating carefully the transformation properties of the dipole moment operator in the D,h group.

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