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Allene formation by the reaction of olefins with propargyl silyl ethers mediated by a zirconocene complex

✍ Scribed by Tamotsu Takahashi; Ryuichiro Hara; Shouquan Huo; Yasuyuki Ura; Mathew P. Leese; Noriyuki Suzuki

Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 197 KB
Volume: 38
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)10319-7

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✦ Synopsis

Ethylene and styrene derivatives reacted with various propargylic ethers in the presence of zirconocene(II) to afford allenic products in high yields. The reaction proceeded via formation of

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