All-Solid-State Potentiometric Sensors for Potassium and Sodium Based on Poly(pyrrole) Solid Contact
β Scribed by A. Michalska; A. Hulanicki; A. Lewenstam
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 55 KB
- Volume
- 57
- Category
- Article
- ISSN
- 0026-265X
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β¦ Synopsis
Potentiometric sensors for potassium or sodium with internal poly(pyrrole) contact and plastic PVC membrane comprising commercially used ionophores were developed and investigated. The all-solid-state electrodes obtained exhibit Nernstian responses and stability superior over the coated wire electrodes. In the case of both electrodes, selectivity coefficients are slightly better compared to those of internal solution electrodes. The dependence of selectivity on the contacting layer ion-exchange properties was observed. The all-solid-state electrodes obtained were successfully applied in standard serum analysis.
π SIMILAR VOLUMES
Hydrogen ion selective solid contact electrode based on tribenzylamine have shown the best Nernstian slope, selectivity and the widest response range in Tris buffered pH sample solutions. Their linear dynamic range was pH 2.48-11.21 and Nernstian slope showed 55.1 mV=pH (at 20 AE 0.2 C). When it was