(Alkynyl)dicobalt Hexacarbonyl-Mediated Radical Cyclizations
β Scribed by Karen L. Salazar; Kenneth M. Nicholas
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- French
- Weight
- 315 KB
- Volume
- 56
- Category
- Article
- ISSN
- 0040-4020
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π SIMILAR VOLUMES
A general, highly selective route to skipped (1,4) diynes, including the hitherto unknown 3-substituted derivatives, is provided by the reactions of (propargyl acetate)Co2(C0)6 complexes with trialkynyl alanes and subsequent demetallation.
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A phenomenon of long-standing interest in organometallic chemistry is the tremendously enhanced stability of carbenium ions flanked by organotransition metal moieties.