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Alkynylcyclopropanes from Terminal Alkynes through Consecutive Coupling to Fischer Carbene Complexes and Selective Propargylene Transfer

✍ Scribed by Prof. Dr. José Barluenga; Eva Tudela; Dr. Rubén Vicente; Dr. Alfredo Ballesteros; Prof. Dr. Miguel Tomás

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
205 KB
Volume
17
Category
Article
ISSN
0947-6539

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ChemInform Abstract: Alkynylcyclopropane
ChemInform Abstract: Alkynylcyclopropanes from Terminal Alkynes Through Consecutive Coupling to Fischer Carbene Complexes and Selective Propargylene Transfer.
✍ Jose Barluenga; Eva Tudela; Ruben Vicente; Alfredo Ballesteros; Miguel Tomas 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 55 KB

## Abstract A very efficient protocol for accessing alkynylcyclopropanes combines the coupling of a terminal alkyne with a simple Fischer carbene complex followed by the regio‐ and stereoselective cyclopropanation reaction with non‐activated alkenes and cyclic dienes.