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Alkyne hydration promoted by RhCl3 and quaternary ammonium salts

โœ Scribed by Jochanan Blum; Hagai Huminer; Howard Alper


Book ID
103693833
Publisher
Elsevier Science
Year
1992
Weight
551 KB
Volume
75
Category
Article
ISSN
0304-5102

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Double bond migration, cyclohexadiene di
โœ Merav Setty-Fichman; Yoel Sasson; Jochanan Blum ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 984 KB

Polystyrene-supported ion pairs, generated from RhCl, and Dowex@ 1 anion exchangers were shown to be efficient, leach-proof and recyclable catalysts for double bond migration in allyhc compounds, disproportionation of 1,3-cyclohexadiene and hydration of aromatic acetylenes. At 50-70ยฐC the isomerizat