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Alkyne-containing chelating ligands: synthesis, properties and metal coordination of 1,2-di(quinolin-8-yl)ethyne

✍ Scribed by Greco, Nicholas J.; Hysell, Michelle; Goldenberg, Joseph R.; Rheingold, Arnold L.; Tor, Yitzhak

Book ID
120429459
Publisher
Royal Society of Chemistry
Year
2006
Tongue
English
Weight
225 KB
Volume
19
Category
Article
ISSN
1477-9226

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Two new polynuclear complexes of Cu II , [Cu 2 (fum)(Β΅-OH)(bpy) 2 (H 2 O)](NO 3 )β€’2H 2 O (1) (fum = fumarate dianion, bpy = 2,2Ј-bipyridine) and [Cu(fum)(tmen)]β€’2H 2 O (2) (tmen = N,N,NЈ,NЈ-tetramethylethane-1,2-diamine), have been synthesized and structurally characterized by X-ray crystallography.