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Alkyne complexes of tungsten(II) containing carboxylate and sulfonate substituted pyridine ligands. Water-soluble alkyne complexes of tungsten(II)

✍ Scribed by Paul K Baker; Alyn E Jenkins; Margaret M Meehan

Book ID
108427958
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
84 KB
Volume
19
Category
Article
ISSN
0277-5387

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Equimolar quantities of [MI2(CO)3(NCMe)2 ] (M = Mo or W) and C3H4N2 (pyrazole) react in CH2C12 at room temperature to give the iodo-bridged dimers [M(#-I)(CO)3(C:~H~N2)]2 (I) and (2). Two equivalents of C3H4N 2 react with [MIz(CO)a(NCMe)2] (M = Mo or W) to give the bis(pyrazole) complexes [MIz(CO)3(