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Alkylvinyl tellurides from tellurium, acetylene and alkyl halides

โœ Scribed by B.A. Irofimov; N.K. Gusarova; A.A. Tatarinova; V.A. Potapov; L.M. Sinegovskaya; S.V. Amosova; M.G. Voronkov

Book ID
104205148
Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
542 KB
Volume
44
Category
Article
ISSN
0040-4020

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โœฆ Synopsis

Abstraot -Synthetic routes to alkylvinyl tellurides by direct reaction of metallio tellurium, acetylene and alkyl halide in the system KOH-SnCl -4 0 and successive interaction of &vinyl telluride with lithium &d2alkyl halide in liquid ammonia have been developed.

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โœ Toru Inoue; Toshiaki Mogami; Nobuaki Kambe; Akiya Ogawa; Noboru Sonoda ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 379 KB

Lithium amides reacted with tellurium under atmospheric pressure of carbon monoxide to yield lithium carbamotelluroates which were trapped with alkyl halides to give Te-alkyl carbamotelluroates in good yields. Results of control experiments suggested that lithium carbamotelluroates were formed by th