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Alkylsilyl isoselenocyanate. A new silicon pseudohalide. Synthesis, characterization, and reaction with carbonyl compounds

✍ Scribed by Sukata, Kazuaki

Book ID
120516528
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
577 KB
Volume
54
Category
Article
ISSN
0022-3263

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Lithium diorganocuprates are now widely used in conjugate additions to a,a-unsaturated car-bony1 compounds' and in coupling reactions with alkyl halides2, allyli~acetates~, and other compounds possessing good leaving groups. Here we report a new reaction of lithium dialkylcuprates which is formally