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Alkylidyne(carbaborane) complexes of the Group 6 metals. Part 5. Protonation studies on [NEt4][W(?CC6H4OMe-2)(CO)2(?5-C2B9H9Me2)]

✍ Scribed by Jeffery, John C.; Li, Sihai; Sams, David W. I.; Stone, F. Gordon A.


Book ID
111863573
Publisher
The Royal Society of Chemistry
Year
1992
Tongue
English
Weight
936 KB
Volume
5
Category
Article
ISSN
1472-7773

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Chemistry of polynuclear metal complexes
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✍ John C. Jeffery; Mark D. Mortimer; F.Gordon A. Stone 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 924 KB

Treatment of [tram-PtH(Cl)(PEt&], in tetrahydrofuran at -30 "C, with [NEt,][Mo(=CCJ&Me-4)(CO),(q' -&B&Me,)], in the presence of TlBF,, affords the thermally labile complex [MoPt(CO),(PEt&{$-~B&(CH,C,&Me-4)Me2}]. Addition of donor molecules L [CO, PEt, or dppm (Ph2PCH,PPh2)] to the latter at low temp