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Alkylation via tris(dialkylamino)sulfonium enolates

โœ Scribed by R. Noyori; I. Nishida; J. Sakata

Publisher
Elsevier Science
Year
1980
Tongue
French
Weight
209 KB
Volume
21
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Tris(dialkylamino)sulfonium enolates generated from tris(diethylamino)sulfonium difluorotrimethylsiliconate and enol silyl ethers are readily alkylated by various alkyl halides under mild conditions. Recently we have demonstrated that reaction of tris(diethylamino)sulfonium (TAS) difluorotrimethylsiliconate (I) and an enol silyl ether II in TRF produces the TAS enolate, III, in

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