Quantitative kinetics for the alkylation reactions of phenol and p-cresol with tert-butyl alcohol in near-critical water as a function of temperature are reported. The reaction products of the alkylation reactions were ortho-and para-substituted phenols, which are used extensively as antioxidants in
β¦ LIBER β¦
Alkylation Reactions in Near-Critical Water in the Absence of Acid Catalysts
β Scribed by Chandler, Karen; Deng, Fenghua; Dillow, Angela K.; Liotta, Charles L.; Eckert, Charles A.
- Book ID
- 121326782
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 135 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0888-5885
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## Abstract The reduction of pyruvic acid in near-critical water has successfully been conducted under conditions of various temperatures, pressures, reaction time and the presence of formic acid as the reducing agent. In this work, additives (K2CO3, KHCO3, and sodium acetate) used in the reduction