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Alkylation of pyridine with tert-butyllithium. Convenient syntheses of 2,6-di-tert-butylpyridine and 2,4,6-tri-tert-butylpyridine

✍ Scribed by Scalzi, Francis V.; Golob, Norman F.


Book ID
120502441
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
319 KB
Volume
36
Category
Article
ISSN
0022-3263

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SOME time ago we have shown that the sulphonic acid obtained in the remarkable sulphonation of 2,6-di-tert.-butylpyridine (I) with sulphur trioxide in liquid sulphur dioxide at -10' according to Brown and Kanner -1 is not the b-derivative (III) as suggested by these investigators but the 34erivative